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Scientists have figured out how to turn any plastic waste into propane

Yulia PoteriankoNews
New catalyst precisely separates chains of plastic molecules into propane molecules. Source: MIT

Plastic pollution is one of the main environmental problems right now. Its main difficulty lies not in the fact that not many people hand over plastic items for recycling but in the fact that until now there has been no perfect technology for this very recycling and a lot of waste has remained dead weight.

The key problem is that there are many types of plastics that require different chemical processes to turn them into a reusable form. And it turns out that sorting a huge number of bottles, containers, and household items becomes economically impractical. And now, scientists at the Massachusetts Institute of Technology have reported that the necessary technology has been found.

They have developed a chemical process using a metal-based catalyst called cobalt that effectively breaks down various plastics, including the most popular types of polyethylene and polypropylene, into propane, one of the main components of household gas or automotive fuel. In addition, the resulting propane can be used to make new plastics, providing at least a partially closed-loop system for plastic recycling.

The new catalyst easily overcomes the key problem of plastic recycling. The long-chain molecules of such materials hold together carbon bonds that are difficult to break to turn plastic into simpler materials suitable for further use. Existing methods of breaking these bonds produced a random mixture of different molecules that required further complex purification and separation into usable compounds. It was impossible to control exactly where the plastic molecule would break.

The catalyst invented by MIT scientists is made of a microporous material called zeolite. It contains cobalt nanoparticles and can selectively destroy a variety of plastic molecules, converting more than 80% of the raw material into propane.

Scientists feared that zeolite would interact poorly with plastic, but it turned out that this material is not only able to pass through polymer molecules but can also break them in such a way as to cut off exactly one molecule of propane. The reaction does not produce unwanted explosive methane. The feedstock can be passed through this catalyst as long as necessary as it will produce propane again.

The advantage of the method is that the materials needed for plastic processing - zeolite, cobalt and hydrogen - are quite cheap and widely available. The catalyst is currently being tested, and engineers are already improving its use to make the method available for industrial-scale plastic recycling. The challenge so far is to determine how much the raw materials are contaminated by inks, adhesives, and label materials used, for example, in the production of plastic packaging. And how they can affect the initial reaction product.

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